I dunno, do you have GH/KH balance problem or a pH problem? Silicate sand should be inert, unless there's something rotting in the sand - do you stir it every month or so?
If something is chewing up your buffer (KH) in just one tank, then this should show up in your KH tests as well as the pH tests. If the pH is falling because the KH is falling then you need to find out what's causing the KH to be used up rather than just adding more buffer - like I said, sort out the cause rather than treat the symptom.
Maybe the filters need a complete clean out, maybe a partial tear down would reveal the culprit? You don't have any new bogwood do you or recently recharged the CO2?